Air quality co-benefits of climate policy

Air pollution is the leading global environmental health risk factor according to the World Health Organization. Implementing policies that reduce greenhouse gas emissions can also reduce the outdoor levels of air pollutants that harm human health by targeting the same emission sources. Dr. Rebecca Saari, an Assistant Professor at the University of Waterloo, presented the relationship between climate policies and health co-benefits at the SOCAAR seminar held on March 2, 2016. Continue reading

Chronic Exposure to Atmospheric Secondary Organic Particulate Matter Enhances Airway Hyper – responsiveness to Methacholine

It’s well known that exposure to air pollution increases the likelihood and health problems linked to cardiorespiratory diseases. Air pollutants consist of a mixture of gases and particulate matter such as secondary organic aerosols (SOA). SOA are formed through the oxidation of natural sources like plants and trees, as well as from industry emissions like naphthalene. Continue reading

Measurements and Modeling of Ultrafine Particulate Matter in California

Photo source: Berkeley Lab’s Environmental Energy Technologies Division

Toxicological studies have consistently found that ultrafine particles are potentially harmful. Yet only recent epidemiological studies have been able to link ultrafine particles to negative public health effects. The difficulty in finding effects in epidemiological studies may be in part because of the population exposure metrics used in previous studies. In the December 2 SOCAAR Seminar Dr. Michael J. Kleeman, a professor at UC Davis’ Department of Civil and Environmental Engineering, presented 15 years of research on the measurements and modeling of ultrafine particular matter in California. Continue reading

Exploring the connections between aerosols and clouds in the high Arctic summer

Photo credit: Julia Burkart

It’s well known that the Arctic climate is influenced by anthropogenic contributions like heating during the winter and regional sources in the summer. But the chemistry of the aerosol environment and its influence on the cloud formation over the Arctic is less understood. Dr. Julia Burkart and Megan Willis, a postdoctoral fellow and Ph.D. student respectively, at the University of Toronto’s Department of Chemistry presented findings from their NETCARE summer aircraft campaign in Resolute Bay, Nunavut at the SOCAAR Seminar held on November 5. Continue reading

Air quality monitoring in Megacities

Dr. Roberto Guardani, a professor at Brazil’s University of São Paulo, gave a special SOCAAR Seminar on October 16, 2015 on the air quality monitoring studies of the São Paulo Metropolitan Area.

The unstable meteorological conditions due to São Paulo’s proximity to the sea makes it difficult to predict the pollutant levels in the area. But Guardani and his research team have worked closely with São Paulo’s Environmental Authority to develop various statistic models to predict ground-level air pollutants from industrial emissions. In his talk, Guardani identified ozone to be the main pollutant in São Paulo, which behaves independently from other pollutants like SO2. He also presented the usage of a neural network-based statistical model, consisting of meteorological variables, to predict the ozone levels and maximum ozone concentrations across the city. Continue reading

Investigating the Role of Transportation Models in Epidemiologic Studies of Traffic Related Air Pollution and Health Effects

It’s widely known that traffic related air pollution is associated with long-term health effects like cancers, cardiovascular or respiratory illnesses. But there’s more that could be learned about the short-term exposure to traffic-related air pollution.  In the first SOCAAR Seminar for 2015-16, Marianne Hatzopoulou, Associate Professor in the Department of Civil Engineering at the University of Toronto discussed the application of transportation and emission models to investigate air pollution in the city of Montreal. The main research questions presented were: i) How can we improve measures of exposure? ii) What is the role of integrated transportation-dispersion models? Can transportation models replace atmospheric dispersion modelling? Continue reading

Clean Air Combustion

Combustion engines are crucial for many industries including transportation, construction, and electric power generation. But are also sources of gaseous and particulate matter emissions. Jim Wallace, a Professor in the Department of Mechanical & Industrial Engineering at the University of Toronto, discuss the sources of these emissions and present the technologies for controlling them at the SOCAAR Seminar on January 7.

Wallace explains it’s all about mixing and the air to fuel ratio when it comes to particle formation. Particles form from combustion processes where there’s inadequate mixing or there’s not enough oxygen present even though the fuel and air are mixed.

For example, gasoline engines don’t generate particles because the fuel and air are mixed and there’s enough oxygen. On the other hand, diesel engines form particles. Designers for a diesel engine can improve oxygen entrainment by: decreasing the temperature, increasing the fuel injection pressure; or reducing the nozzle diameter. Engine manufacturers already do this, but there’s a limit to what they can do.

An advance in engine design is the gasoline direct injection (GDI) engine. A key advantage of the GDI engine is that it enables reduced fuel consumption. Like a diesel engine, it has a fuel injector which sprays fuel directly into the combustion chamber. Rather than spraying fuel into a port and then waiting for something to happen, the fuel is sprayed right into the place where it burns. The GDI engine has increases volumetric efficiency, reduces pumping loss due to stratified operation (one region has a different air to fuel ratio than another), and can use a smaller engine with same power output.

However, the GDI engine has two main problems associated with increased particulate emissions.
First, the injected fuel doesn’t have enough time to vaporize and properly mix, producing liquid droplets and getting particle swarm. Second, fuel can spray on top of the piston and cylinder walls and interact; getting a pool of gasoline on top of the piston and that can cause a pool fire.

Wallace showed that GDI engines under certain operation modes can produce an order of magnitude more particles than conventional gasoline engines. He believes this particulate emission is a significant challenge for the industry, as the GDI engine makes up a large portion of new productions.

Results from Wallace and his research team show fuel composition has a huge affect on GDI particulate matter emissions. They correlate emissions of isobutylene and toluene with the observed variability in particulate measurements. The next step in for the research team will be to run experiments with surrogate fuels where the exact fuel composition is known and refine this correlation.

Near-road measurement of traffic-related pollutants

Photo Source: Wikipedia user Aliamizi

Photo Source: Wikipedia user Aliamizi

Traffic related pollutants were officially classified as carcinogenic by the World Health Organization in 2013. For the many Canadians that live or work near roadways, this could be a risk factor which may negatively impact their health.

Dr. Cheol-Heon Jeong and Jon Wang, both of UofT’s Department of Chemical Engineering and Applied Chemistry, say the concentration of traffic-related pollutants varies with distance from the road; where significant pollution can be detected up to 250 metres from the road. Continue reading

Characterization of atmospheric black carbon in Toronto and the oil sands region

Human activities like burning fossil fuels and vehicle emissions generate of variety of aerosol particles like black carbon, organic, sulphate, and nitrate particles. The interaction between black carbon and other aerosol particles can change the physical and chemical properties, such as light absorption of black carbon particles. Understanding the chemical nature of these aerosol particles is important in evaluating their environmental impacts. Continue reading

Real-time characterization of soot particles

Soot particles are seen everywhere from city centres to the Alps. There’s ongoing debate on the nature and dynamic evolution of these particles in atmosphere. Soot are light-absorbing, chemically and morphologically complex particles that contribute to air pollution and can have negative health effects. Soot particles are emitted from flames and engines and are highly regional pollutants. Continue reading